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Alumina (Al2O3), Aluminum Oxide

Alumina, or aluminum oxide (Al2O3), with its molecular weight of 102, is a foundational element in the realm of technical ceramics, boasting an impressive high melting point of 2,072℃. This makes it the most prevalent ceramic material used across industries, renowned for its role as a traditional yet essential material. The high-purity aluminum oxide version of alumina finds extensive applications in a variety of sectors, credited to its comprehensive utility and adaptability. Its widespread use in technology and industry is attributed to alumina's exceptional properties, including superb electrical insulation, high thermal conductivity, and strong chemical resistance, which collectively make it a versatile and indispensable material.

Moreover, the characteristics of alumina such as good wear resistance and low thermal expansion further enhance its suitability for diverse applications, ensuring components made from alumina can endure extreme conditions and mechanical stress. This positions alumina as a critical resource in applications demanding high durability and reliability. From its insulating properties crucial in electronics to its wear resistance vital in mechanical systems, and thermal conductivity essential for thermal management, alumina's multifaceted performance solidifies its standing as a key material in pushing the boundaries of modern industry and technological innovation.

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Alumina Structure

Alumina, or aluminum oxide (Al2O3), possesses a crystalline structure that significantly contributes to its wide range of impressive properties, making it a staple in the field of technical ceramics. The most common and thermodynamically stable form of alumina under normal conditions is the alpha phase (α-Al2O3), which is characterized by a hexagonal close-packed structure. In this structure, aluminum ions are surrounded by six oxygen ions in an octahedral arrangement, creating a dense and tightly packed lattice that is responsible for alumina's high hardness, melting point, and chemical stability.

The oxygen ions in the alpha-alumina structure form a nearly hexagonal close-packed arrangement, while the aluminum ions fill two-thirds of the octahedral sites within the oxygen lattice. This configuration leads to a high degree of ionic bonding with some covalent character, due to the electronegativity differences between aluminum and oxygen. This bond strength is a key factor behind alumina's excellent mechanical properties, including its resistance to wear and corrosion. Additionally, the stability of the alpha phase contributes to alumina's ability to withstand high temperatures without significant deformation or breakdown, making it an ideal material for high-temperature applications in various industries, from electronics to aerospace.

Read more: Everything You Need to Know about Alumina Ceramics

Alumina Specifications

Material Alumina
Properties Units AL997 AL995 AL99 AL95
%Alumina - 99.70% 99.50% 99.00% 95.00%
Color - Ivory Ivory Ivory Ivory & White
Permeability - Gas-tight Gas-tight Gas-tight Gas-tight
Density g/cm3 3.94 3.9 3.8 3.75
Straightness - 1‰ 1‰ 1‰ 1‰
Hardness Mohs Scale 9 9 9 8.8
Water Absorption - ≤0.2 ≤0.2 ≤0.2 ≤0.2
Flexural Strength(Typical 20℃) Mpa 375 370 340 304
Compressive Strength
(Typical 20℃)
Mpa 2300 2300 2210 1910
Coefficient of Thermal Expansion
(25℃ to 800℃)
0-6/℃ 7.6 7.6 7.6 7.6
Dielectric Strength (5mm Thickness) AC-kv/mm 10 10 10 10
Dielectric Loss
25ºC@ 1MHz
- < 0.0001 < 0.0001 0.0006 0.0004
Dielectric Constant 25º C@ 1MHz 9.8 9.7 9.5 9.2
Volume Resistivity (20℃)
(300℃)
Ω·cm³ >1014
2*1012
>1014
2*1012
>1014
4*1011
>1014
2*1011
Long-term Operating Temperature 1700 1650 1600 1400
Thermal Conductivity (25℃) W/m·K 35 35 34 20

Alumina Formulations

ACM's product formulations are developed to address the varied application problems in which ceramic components are commonly used. Many industrial applications push the envelope on specific requirements leading to the development of new formulations to successfully address them.

Properties Unit Fused Alumina Reactive Grade Alumina Ready To Press Alumina (RTP Alumina) Activated Alumina
Al2OContent % 95.5 99.8 98 96 94 92 90
Bulk Density g/cm3 3.95 ~600 ~1000 ~600 ~1100 ~900 ~1200 ~1100
Grain Size μm Customized Customized ≈130 ≈170 ≈100 ≈200 customized
Color White White White White
Melting Point 2000
Hardness Mohs 9
Specific Surface Area m2/g 0.2-0.5 3.5-5 2-3 6-9 6-10 200-260

Corundum vs. Alumina vs. Cordierite vs. Mullite

Alumina Applications in Various Industries

1. Industrial Appliances
Alumina ceramics are critical in the manufacturing of components for industrial appliances due to their high thermal stability and resistance to wear and corrosion. This includes use in furnaces and as thermal couple protectors, where their ability to withstand extreme temperatures is essential.

2. Coatings
High-purity alumina provides excellent protective coatings for various applications, offering resistance to abrasion, corrosion, and thermal shock. These coatings are particularly valuable in extending the life and performance of equipment in harsh environments.

3. Labware
Alumina's chemical inertness and high melting point make it suitable for labware, such as crucibles and mortars and pestles, used for grinding and heating chemical compounds in laboratories.

4. Engineered Ceramics
Engineered alumina ceramics serve in advanced applications, including CVD processes, ion implants, photolithography, and semiconductor manufacturing, where parts require high purity and precision.

5. Refractories
Alumina's high melting point and resistance to thermal shock make it an ideal material for refractories used in the lining of furnaces, kilns, and reactors in various industrial sectors.

6. Artificial Bones and Joints
Due to its excellent biocompatibility, high strength, and wear resistance, alumina ceramics are used in medical applications to manufacture artificial bones and joints, enhancing the quality of life for patients.

7. Abrasives
The extreme hardness of alumina ceramics makes them perfect for abrasive applications, including grinding media and abrasive tools, where they outperform metals in durability and efficiency.

8. Consumer Electronics
Alumina's electrical insulation properties and thermal management capabilities are leveraged in consumer electronics, providing critical components such as insulators, substrates, and enclosures.

9. Traditional Industry Applications
In traditional industries, alumina ceramics are utilized in products like injector tubes, gas nozzles, and insulators, benefiting from their hardness and thermal resistance.

10. Grinding and Polishing Tools
Alumina's hardness and durability also make it the material of choice for grinding and polishing tools, including mortars and pestles widely used in laboratory settings for preparing samples.

Alumina ceramics stand out for their versatility across a broad spectrum of applications, from high-tech engineering and semiconductor manufacturing to traditional industries and medical prosthetics. Their unique combination of thermal stability, mechanical strength, and chemical inertness allows alumina products to meet the demanding requirements of various fields, driving innovation and enhancing performance in countless applications.

ACM Ceramic Product Categories

Your Alumina Ceramics Supplier

Advanced Ceramic Materials (ACM) is a leading supplier of alumina ceramic products of the highest quality for various applications. We are happy to provide advice on materials, design, and application. Feel free to contact us with questions about Al2O3 or other ceramic materials not listed on the website. 

FAQs
How Are Alumina Components Made?

Alumina ceramics are typically manufactured from bauxite and can be shaped using injection molding, die pressing, isostatic pressing, slip casting, diamond machining, and extrusion. Like aluminum nitride and other important engineering materials, alumina can be produced by dry press and sinter or by hot pressing using appropriate sintering aids.

Do You Supply Customized Al2O3 Components?

We can supply customized products according to the drawings you provide, and our engineers can also provide technical support and advice for your design.

What Are the Characteristics of Aluminum Oxide?

Aluminum Oxide is characterized by high hardness, excellent resistance to corrosion, thermal stability, good dielectric properties (for converting from DC to GHz frequencies), low loss tangent, and stiffness. See the next section for more details on the properties of alumina ceramic materials.

What Are the Different Types of Aluminum Oxide Ceramic?

Depending on the content of Al2O3 and additives used, there are different series of aluminum oxide mateials. Based on the Al2O3 content, alumina can be categorized as 75% alumina, 85% alumina, 95% alumina, 99% alumina, and so on. Based on the difference in crystal phase, there are mullite, corundum-mullite, and corundum; Based on the variety of additives used, there is the chromium corundum, titanium corundum, etc.

What Are the Differences Between Zirconia Toughened Alumina (zta) and Alumina Toughened Zirconia (atz)?

While both ZTA and ATZ have the same raw materials, it is important not to confuse the two composites. In alumina toughened zirconia (ATZ), the ratio of alumina to zirconia is low. In zirconia toughened alumina (ZTA), the opposite is the case.

Why Is Alumina Used in Refractories?

Due to its high melting point and resistance to thermal shock, alumina is an ideal material for refractories used in furnace linings, kilns, and incinerators, where it can withstand extreme temperatures.

How Does Alumina Compare to Other Ceramic Materials?

Alumina offers a superior combination of hardness, thermal stability, and chemical resistance compared to many other ceramic materials, making it more versatile and widely applicable in various industries.

Is Alumina Environmentally Friendly?

Alumina is inert and non-toxic, posing minimal environmental impact. Its durability and recyclability further contribute to its environmental friendliness in various applications.

Properties
Chemical Formula Al2O3
Mechanical
Density 3.9 g/cm3
Hardness 17.2 GPa
Modulus of Elasticity 380 GPa
Flexural Strength 380 MPa
Compressive Strength 2450 MPa
Poisson's Ratio 0.23
Fracture Toughness 4 MPa m½
Electrical
Dielectric Strength 15 ac V/mm
Dielectric Constant 9.9 (@ 1 MHz)
Volume Resistivity 10^14 ohm-cm
Thermal
Coefficient of Thermal Expansion 7.2 x 10^-6/°C
Thermal Conductivity 37 W/(m*K)
Specific Heat 780 J/(Kg*K)
Shock Resistance 250 °C Diff.
Maximum Working Temperature 1700 °C
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